How does strength of boric acid solution increase in presence of salicylic acid?












8












$begingroup$


A while ago, I read that salicylic acid can make boric acid solution strongly acidic when it's added to it.



To my knowledge, I know that boric acid becomes a strong acid in presence of cis-diols (except ethylene glycol). I also know that it happens due to increased stability of conjugate base by chelation using polyhydroxy compounds.



But I can't really make out the case with salicylic acid. I will be really thankful if you could shed some light on this topic.






inorganic-chemistry acid-base







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  • $begingroup$
    see: nrcresearchpress.com/doi/pdf/10.1139/v77-421
    $endgroup$
    – MaxW
    23 hours ago
















8












$begingroup$


A while ago, I read that salicylic acid can make boric acid solution strongly acidic when it's added to it.



To my knowledge, I know that boric acid becomes a strong acid in presence of cis-diols (except ethylene glycol). I also know that it happens due to increased stability of conjugate base by chelation using polyhydroxy compounds.



But I can't really make out the case with salicylic acid. I will be really thankful if you could shed some light on this topic.






inorganic-chemistry acid-base







share|improve this question









New contributor




Richeek is a new contributor to this site. Take care in asking for clarification, commenting, and answering.
Check out our Code of Conduct.







$endgroup$












  • $begingroup$
    see: nrcresearchpress.com/doi/pdf/10.1139/v77-421
    $endgroup$
    – MaxW
    23 hours ago














8












8








8





$begingroup$


A while ago, I read that salicylic acid can make boric acid solution strongly acidic when it's added to it.



To my knowledge, I know that boric acid becomes a strong acid in presence of cis-diols (except ethylene glycol). I also know that it happens due to increased stability of conjugate base by chelation using polyhydroxy compounds.



But I can't really make out the case with salicylic acid. I will be really thankful if you could shed some light on this topic.






inorganic-chemistry acid-base







share|improve this question









New contributor




Richeek is a new contributor to this site. Take care in asking for clarification, commenting, and answering.
Check out our Code of Conduct.







$endgroup$




A while ago, I read that salicylic acid can make boric acid solution strongly acidic when it's added to it.



To my knowledge, I know that boric acid becomes a strong acid in presence of cis-diols (except ethylene glycol). I also know that it happens due to increased stability of conjugate base by chelation using polyhydroxy compounds.



But I can't really make out the case with salicylic acid. I will be really thankful if you could shed some light on this topic.






inorganic-chemistry acid-base




inorganic-chemistry acid-base






share|improve this question









New contributor




Richeek is a new contributor to this site. Take care in asking for clarification, commenting, and answering.
Check out our Code of Conduct.











share|improve this question









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Check out our Code of Conduct.









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edited 20 hours ago









andselisk

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asked 23 hours ago









RicheekRicheek

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Richeek is a new contributor to this site. Take care in asking for clarification, commenting, and answering.
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  • $begingroup$
    see: nrcresearchpress.com/doi/pdf/10.1139/v77-421
    $endgroup$
    – MaxW
    23 hours ago


















  • $begingroup$
    see: nrcresearchpress.com/doi/pdf/10.1139/v77-421
    $endgroup$
    – MaxW
    23 hours ago
















$begingroup$
see: nrcresearchpress.com/doi/pdf/10.1139/v77-421
$endgroup$
– MaxW
23 hours ago




$begingroup$
see: nrcresearchpress.com/doi/pdf/10.1139/v77-421
$endgroup$
– MaxW
23 hours ago










2 Answers
2






active

oldest

votes


















15












$begingroup$

boric acid and salicylic acid



Equilibrium will be far to the right, as a stable six membered ring is formed. The proton speaks for itself.




References: Queen, A. The kinetics of the reaction of boric acid with salicylic acid. Can. J. Chem. 1977, 55 (16), 3035–3039 DOI: 10.1139/v77-421.






share|improve this answer











$endgroup$





















    3












    $begingroup$

    By googling "boric acid salicylic acid"
    I have found the salicylic acid acts like it was a diol toward the boric acid, but just 1:1.



    https://www.nrcresearchpress.com/doi/abs/10.1139/v77-421






    share|improve this answer









    $endgroup$














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      2 Answers
      2






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      2 Answers
      2






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      15












      $begingroup$

      boric acid and salicylic acid



      Equilibrium will be far to the right, as a stable six membered ring is formed. The proton speaks for itself.




      References: Queen, A. The kinetics of the reaction of boric acid with salicylic acid. Can. J. Chem. 1977, 55 (16), 3035–3039 DOI: 10.1139/v77-421.






      share|improve this answer











      $endgroup$


















        15












        $begingroup$

        boric acid and salicylic acid



        Equilibrium will be far to the right, as a stable six membered ring is formed. The proton speaks for itself.




        References: Queen, A. The kinetics of the reaction of boric acid with salicylic acid. Can. J. Chem. 1977, 55 (16), 3035–3039 DOI: 10.1139/v77-421.






        share|improve this answer











        $endgroup$
















          15












          15








          15





          $begingroup$

          boric acid and salicylic acid



          Equilibrium will be far to the right, as a stable six membered ring is formed. The proton speaks for itself.




          References: Queen, A. The kinetics of the reaction of boric acid with salicylic acid. Can. J. Chem. 1977, 55 (16), 3035–3039 DOI: 10.1139/v77-421.






          share|improve this answer











          $endgroup$



          boric acid and salicylic acid



          Equilibrium will be far to the right, as a stable six membered ring is formed. The proton speaks for itself.




          References: Queen, A. The kinetics of the reaction of boric acid with salicylic acid. Can. J. Chem. 1977, 55 (16), 3035–3039 DOI: 10.1139/v77-421.







          share|improve this answer














          share|improve this answer



          share|improve this answer








          edited 1 hour ago









          Gaurang Tandon

          5,33062763




          5,33062763










          answered 22 hours ago









          William R. EbenezerWilliam R. Ebenezer

          67914




          67914























              3












              $begingroup$

              By googling "boric acid salicylic acid"
              I have found the salicylic acid acts like it was a diol toward the boric acid, but just 1:1.



              https://www.nrcresearchpress.com/doi/abs/10.1139/v77-421






              share|improve this answer









              $endgroup$


















                3












                $begingroup$

                By googling "boric acid salicylic acid"
                I have found the salicylic acid acts like it was a diol toward the boric acid, but just 1:1.



                https://www.nrcresearchpress.com/doi/abs/10.1139/v77-421






                share|improve this answer









                $endgroup$
















                  3












                  3








                  3





                  $begingroup$

                  By googling "boric acid salicylic acid"
                  I have found the salicylic acid acts like it was a diol toward the boric acid, but just 1:1.



                  https://www.nrcresearchpress.com/doi/abs/10.1139/v77-421






                  share|improve this answer









                  $endgroup$



                  By googling "boric acid salicylic acid"
                  I have found the salicylic acid acts like it was a diol toward the boric acid, but just 1:1.



                  https://www.nrcresearchpress.com/doi/abs/10.1139/v77-421







                  share|improve this answer












                  share|improve this answer



                  share|improve this answer










                  answered 23 hours ago









                  PoutnikPoutnik

                  75928




                  75928






















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