How does strength of boric acid solution increase in presence of salicylic acid?
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A while ago, I read that salicylic acid can make boric acid solution strongly acidic when it's added to it.
To my knowledge, I know that boric acid becomes a strong acid in presence of cis-diols (except ethylene glycol). I also know that it happens due to increased stability of conjugate base by chelation using polyhydroxy compounds.
But I can't really make out the case with salicylic acid. I will be really thankful if you could shed some light on this topic.
inorganic-chemistry acid-base
edited 20 hours ago
andselisk
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asked 23 hours ago
RicheekRicheek
433
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add a comment |
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A while ago, I read that salicylic acid can make boric acid solution strongly acidic when it's added to it.
To my knowledge, I know that boric acid becomes a strong acid in presence of cis-diols (except ethylene glycol). I also know that it happens due to increased stability of conjugate base by chelation using polyhydroxy compounds.
But I can't really make out the case with salicylic acid. I will be really thankful if you could shed some light on this topic.
inorganic-chemistry acid-base
edited 20 hours ago
andselisk
19k660125
asked 23 hours ago
RicheekRicheek
433
New contributor
Richeek is a new contributor to this site. Take care in asking for clarification, commenting, and answering.
Check out our Code of Conduct.
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see: nrcresearchpress.com/doi/pdf/10.1139/v77-421
$endgroup$
– MaxW
23 hours ago
add a comment |
$begingroup$
A while ago, I read that salicylic acid can make boric acid solution strongly acidic when it's added to it.
To my knowledge, I know that boric acid becomes a strong acid in presence of cis-diols (except ethylene glycol). I also know that it happens due to increased stability of conjugate base by chelation using polyhydroxy compounds.
But I can't really make out the case with salicylic acid. I will be really thankful if you could shed some light on this topic.
inorganic-chemistry acid-base
edited 20 hours ago
andselisk
19k660125
asked 23 hours ago
RicheekRicheek
433
New contributor
Richeek is a new contributor to this site. Take care in asking for clarification, commenting, and answering.
Check out our Code of Conduct.
$endgroup$
A while ago, I read that salicylic acid can make boric acid solution strongly acidic when it's added to it.
To my knowledge, I know that boric acid becomes a strong acid in presence of cis-diols (except ethylene glycol). I also know that it happens due to increased stability of conjugate base by chelation using polyhydroxy compounds.
But I can't really make out the case with salicylic acid. I will be really thankful if you could shed some light on this topic.
inorganic-chemistry acid-base
inorganic-chemistry acid-base
edited 20 hours ago
andselisk
19k660125
asked 23 hours ago
RicheekRicheek
433
New contributor
Richeek is a new contributor to this site. Take care in asking for clarification, commenting, and answering.
Check out our Code of Conduct.
edited 20 hours ago
andselisk
19k660125
asked 23 hours ago
RicheekRicheek
433
New contributor
Richeek is a new contributor to this site. Take care in asking for clarification, commenting, and answering.
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edited 20 hours ago
andselisk
19k660125
edited 20 hours ago
andselisk
19k660125
edited 20 hours ago
andselisk
19k660125
19k660125
asked 23 hours ago
RicheekRicheek
433
New contributor
Richeek is a new contributor to this site. Take care in asking for clarification, commenting, and answering.
Check out our Code of Conduct.
asked 23 hours ago
RicheekRicheek
433
asked 23 hours ago
RicheekRicheek
433
433
New contributor
Richeek is a new contributor to this site. Take care in asking for clarification, commenting, and answering.
Check out our Code of Conduct.
New contributor
Richeek is a new contributor to this site. Take care in asking for clarification, commenting, and answering.
Check out our Code of Conduct.
Richeek is a new contributor to this site. Take care in asking for clarification, commenting, and answering.
Check out our Code of Conduct.
$begingroup$
see: nrcresearchpress.com/doi/pdf/10.1139/v77-421
$endgroup$
– MaxW
23 hours ago
add a comment |
$begingroup$
see: nrcresearchpress.com/doi/pdf/10.1139/v77-421
$endgroup$
– MaxW
23 hours ago
$begingroup$
see: nrcresearchpress.com/doi/pdf/10.1139/v77-421
$endgroup$
– MaxW
23 hours ago
$begingroup$
see: nrcresearchpress.com/doi/pdf/10.1139/v77-421
$endgroup$
– MaxW
23 hours ago
add a comment |
2 Answers
2
active
oldest
votes
$begingroup$
Equilibrium will be far to the right, as a stable six membered ring is formed. The proton speaks for itself.
References: Queen, A. The kinetics of the reaction of boric acid with salicylic acid. Can. J. Chem. 1977, 55 (16), 3035–3039 DOI: 10.1139/v77-421.
edited 1 hour ago
Gaurang Tandon
5,33062763
answered 22 hours ago
William R. EbenezerWilliam R. Ebenezer
67914
$endgroup$
add a comment |
$begingroup$
By googling "boric acid salicylic acid"
I have found the salicylic acid acts like it was a diol toward the boric acid, but just 1:1.
https://www.nrcresearchpress.com/doi/abs/10.1139/v77-421
answered 23 hours ago
PoutnikPoutnik
75928
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add a comment |
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2 Answers
2
active
oldest
votes
2 Answers
2
active
oldest
votes
active
oldest
votes
active
oldest
votes
$begingroup$
Equilibrium will be far to the right, as a stable six membered ring is formed. The proton speaks for itself.
References: Queen, A. The kinetics of the reaction of boric acid with salicylic acid. Can. J. Chem. 1977, 55 (16), 3035–3039 DOI: 10.1139/v77-421.
edited 1 hour ago
Gaurang Tandon
5,33062763
answered 22 hours ago
William R. EbenezerWilliam R. Ebenezer
67914
$endgroup$
add a comment |
$begingroup$
Equilibrium will be far to the right, as a stable six membered ring is formed. The proton speaks for itself.
References: Queen, A. The kinetics of the reaction of boric acid with salicylic acid. Can. J. Chem. 1977, 55 (16), 3035–3039 DOI: 10.1139/v77-421.
edited 1 hour ago
Gaurang Tandon
5,33062763
answered 22 hours ago
William R. EbenezerWilliam R. Ebenezer
67914
$endgroup$
add a comment |
$begingroup$
Equilibrium will be far to the right, as a stable six membered ring is formed. The proton speaks for itself.
References: Queen, A. The kinetics of the reaction of boric acid with salicylic acid. Can. J. Chem. 1977, 55 (16), 3035–3039 DOI: 10.1139/v77-421.
edited 1 hour ago
Gaurang Tandon
5,33062763
answered 22 hours ago
William R. EbenezerWilliam R. Ebenezer
67914
$endgroup$
Equilibrium will be far to the right, as a stable six membered ring is formed. The proton speaks for itself.
References: Queen, A. The kinetics of the reaction of boric acid with salicylic acid. Can. J. Chem. 1977, 55 (16), 3035–3039 DOI: 10.1139/v77-421.
edited 1 hour ago
Gaurang Tandon
5,33062763
answered 22 hours ago
William R. EbenezerWilliam R. Ebenezer
67914
edited 1 hour ago
Gaurang Tandon
5,33062763
edited 1 hour ago
Gaurang Tandon
5,33062763
edited 1 hour ago
Gaurang Tandon
5,33062763
5,33062763
answered 22 hours ago
William R. EbenezerWilliam R. Ebenezer
67914
answered 22 hours ago
William R. EbenezerWilliam R. Ebenezer
67914
answered 22 hours ago
William R. EbenezerWilliam R. Ebenezer
67914
67914
add a comment |
add a comment |
$begingroup$
By googling "boric acid salicylic acid"
I have found the salicylic acid acts like it was a diol toward the boric acid, but just 1:1.
https://www.nrcresearchpress.com/doi/abs/10.1139/v77-421
answered 23 hours ago
PoutnikPoutnik
75928
$endgroup$
add a comment |
$begingroup$
By googling "boric acid salicylic acid"
I have found the salicylic acid acts like it was a diol toward the boric acid, but just 1:1.
https://www.nrcresearchpress.com/doi/abs/10.1139/v77-421
answered 23 hours ago
PoutnikPoutnik
75928
$endgroup$
add a comment |
$begingroup$
By googling "boric acid salicylic acid"
I have found the salicylic acid acts like it was a diol toward the boric acid, but just 1:1.
https://www.nrcresearchpress.com/doi/abs/10.1139/v77-421
answered 23 hours ago
PoutnikPoutnik
75928
$endgroup$
By googling "boric acid salicylic acid"
I have found the salicylic acid acts like it was a diol toward the boric acid, but just 1:1.
https://www.nrcresearchpress.com/doi/abs/10.1139/v77-421
answered 23 hours ago
PoutnikPoutnik
75928
answered 23 hours ago
PoutnikPoutnik
75928
answered 23 hours ago
PoutnikPoutnik
75928
answered 23 hours ago
PoutnikPoutnik
75928
75928
add a comment |
add a comment |
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$begingroup$
see: nrcresearchpress.com/doi/pdf/10.1139/v77-421
$endgroup$
– MaxW
23 hours ago